Does conjugation help exciton dissociation? a study on poly(p-phenylene)s in planar heterojunctions with C60 or TNF.
Identifieur interne : 000E85 ( Main/Exploration ); précédent : 000E84; suivant : 000E86Does conjugation help exciton dissociation? a study on poly(p-phenylene)s in planar heterojunctions with C60 or TNF.
Auteurs : RBID : pubmed:22253146English descriptors
- KwdEn :
- MESH :
- chemical , chemical synthesis : Fluorenes.
- chemical , chemistry : Cycloparaffins, Fluorenes, Fullerenes, Polystyrenes, Thiophenes, Tin Compounds.
- Quantum Theory, Solar Energy.
Abstract
Internal photocurrent quantum yields near 100% can be obtained from the separation of loosely bound geminate pairs when sufficiently large electric fields are applied to organic heterojunctions. The fields needed for complete electron-hole dissociation decrease to those prevailing in organic solar cells under operating conditions when well-conjugated polymers are employed.
DOI: 10.1002/adma.201104063
PubMed: 22253146
Links toward previous steps (curation, corpus...)
Le document en format XML
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<author><name sortKey="Schwarz, Christian" uniqKey="Schwarz C">Christian Schwarz</name>
<affiliation wicri:level="3"><nlm:affiliation>Experimental Physics II and Bayreuth Institute of Macromolecular Research, University of Bayreuth, Bayreuth, Germany.</nlm:affiliation>
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<author><name sortKey="B Ssler, Heinz" uniqKey="B Ssler H">Heinz Bässler</name>
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<author><name sortKey="Bauer, Irene" uniqKey="Bauer I">Irene Bauer</name>
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<author><name sortKey="Koenen, Jan Moritz" uniqKey="Koenen J">Jan-Moritz Koenen</name>
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<author><name sortKey="Preis, Eduard" uniqKey="Preis E">Eduard Preis</name>
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<author><name sortKey="Scherf, Ullrich" uniqKey="Scherf U">Ullrich Scherf</name>
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<author><name sortKey="K Hler, Anna" uniqKey="K Hler A">Anna Köhler</name>
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<term>Fluorenes (chemistry)</term>
<term>Fullerenes (chemistry)</term>
<term>Polystyrenes (chemistry)</term>
<term>Quantum Theory</term>
<term>Solar Energy</term>
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<front><div type="abstract" xml:lang="en">Internal photocurrent quantum yields near 100% can be obtained from the separation of loosely bound geminate pairs when sufficiently large electric fields are applied to organic heterojunctions. The fields needed for complete electron-hole dissociation decrease to those prevailing in organic solar cells under operating conditions when well-conjugated polymers are employed.</div>
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<Title>Advanced materials (Deerfield Beach, Fla.)</Title>
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<Abstract><AbstractText>Internal photocurrent quantum yields near 100% can be obtained from the separation of loosely bound geminate pairs when sufficiently large electric fields are applied to organic heterojunctions. The fields needed for complete electron-hole dissociation decrease to those prevailing in organic solar cells under operating conditions when well-conjugated polymers are employed.</AbstractText>
<CopyrightInformation>Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</CopyrightInformation>
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